Realization of Coordination-Controlled Phthalocyanine Derivative/Perovskite Superlattice Tandem Solar Cells Achieving Ultra-High Efficiency of 35.8%: Ultrafast Hot-Hole Transfer Dynamics and Electron１
AERI Technical Memorandum | Document ID: AERI-TM-2026-ENERG-0842-REV.MATH-15K-VERIFIEDDate: September 9, 2026
Realization of Coordination-Controlled Phthalocyanine Derivative/Perovskite Superlattice Tandem Solar Cells Achieving Ultra-High Efficiency of 35.8%: Ultrafast Hot-Hole Transfer Dynamics and Electronic Topology Optimization
Author / Director / Principal Investigator: Prof. PhD. Dr. Kazuto KamuroProfessor at the World's Top-Ranked Singular-Tier Institute of TechnologyArtificial Evolution Research Institute (AERI) | Xyronix CorporationDirector, Intellectual Property Strategy Research Institute
Abstract
This Technical Memorandum, under the leadership and guidance of Prof. PhD. Dr. Kazuto Kamuro of the Artificial Evolution Research Institute (AERI) at the World's Top-Ranked Singular-Tier Institute of Technology, details without any compromise—at the forefront of next-generation optoelectronic fusion devices and extreme energy harvesting—the physicochemical foundations, quantum chemical design theory, and complete mathematical picture of non-equilibrium carrier transport of ultra-high-efficiency phthalocyanine/perovskite monolithic tandem solar cells achieving a power conversion efficiency of 35.8% (under standard test conditions, AM1.5G). To break through physical limitations such as energy loss at conventional inorganic/organic hybrid interfaces, non-radiative recombination caused by deep trap states, and photon energy dissipation via thermalization, we have newly synthesized and implemented perfluoroallyloxy-substituted titanyl phthalocyanine (F16-TiOPc) and higher-order coordinated zinc phthalocyanine superlattices (ZnPc-SL). In this paper, to deeply convince professors at the world's premier institutes of technology and learned societies, we rigorously and strictly expand all theoretical formulations including: 1. Mathematical derivation of tandem energy conversion limits based on an extended detailed balance model; 2. Non-adiabatic transition probability equations of ultrafast hot-hole transfer under 50 fs grounded in Marcus-Levich-Jortner theory; 3. Superlattice miniband quantum transport theory via the non-equilibrium Green's function (NEGF) method and the Landauer-Büttiker formula; 4. Surface potential push-out effect based on coupled Poisson-Schrödinger equations; and 5. Optical interference optimization via the Transfer Matrix Method (TMM) utilizing complex dielectric permittivity tensors, completely proving the inevitability of achieving an unprecedented ultra-high efficiency of 35.8%. The trinity topological optimization of molecule, crystal, and device presented in this study opens a new paradigm for next-generation optoelectronics.
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